Ranked by ungraded value · updated Nov 12, 2026

The Most Expensive POP Series 4 Cards

The 17 cards of POP Series 4 (2006), ranked by current ungraded value. The top three today are Deoxys ex 17/17 ($1,000), Chimecho δ 1/17 ($946) and Pokémon Fan Club 9/17 ($475).

The full checklist, with every card’s price, is in the POP Series 4 price guide. It is part of the EX era. Across every set, see the most valuable Pokémon cards.

Ranked: 17 English cards
Order: Ungraded value, high to low
Condition: Ungraded

The top 3

#1
Deoxys ex
POP Series 4 · 17/17
$1,000
PSA 10 $17,306
#2
Chimecho δ
POP Series 4 · 1/17
$946
PSA 10 $11,700
#3
Pokémon Fan Club
POP Series 4 · 9/17
$475
PSA 10 $2,650

The top 17, ungraded

Sort by

1
Deoxys ex
EXPOP Series 417/172006Rare
$1,000
Ungraded
PSA 10 $17,306
Strong data
Deoxys ex shows the Speed Forme crouched low against a stormy purple sky, a white lightning bolt splitting the clouds behind it while dark shards scatter through the air. The angular CGI-style rendering, art by Hiromichi Sugiyama, suits the alien Pokémon well. As the top card of a small POP Series promo set, it draws ex-era collectors and Deoxys fans chasing every Forme.
2
Chimecho δ
EXPOP Series 41/172006Rare
$946
Ungraded
PSA 10 $11,700
Moderate data
3
Pokémon Fan Club
EXPOP Series 49/172006Uncommon
$475
Ungraded
PSA 10 $2,650
Moderate data
4
Mew
EXPOP Series 44/172006Rare
$375
Ungraded
PSA 10 $4,068
Strong data
5
Sceptile
EXPOP Series 45/172006Rare
$233
Ungraded
PSA 10 $1,536
Strong data
Sceptile leans forward out of a soft-focus forest, its yellow eyes narrowed and head lowered in a close crop, with sunlight breaking through the green leaves behind it. Art by Atsuko Nishida gives the scene a painterly, almost photographic depth. As a holo rare from the small POP Series promo sets of the ex era, this Sceptile draws fans of the Hoenn grass starter and of that period's distinctive card design.
6
Deoxys δ
EXPOP Series 42/172006Rare
$200
Ungraded
PSA 10 $2,475
Strong data
7
Squirtle
EXPOP Series 414/172006Common
$74.20
Ungraded
PSA 10 $1,420
Strong data
Squirtle peeks out at you with wide brown eyes and a small grin, its body softened into pale, glowing blues and creams as if seen through mist or splashing water. Art by Atsuko Nishida gives this Common from POP Series Four a dreamy, painterly feel. Squirtle fans and set completers chase it, since the promo-style POP packs were never as easy to find as main expansions.
8
Pikachu
EXPOP Series 413/172006Common
$71.99
Ungraded
PSA 10 $2,039
Moderate data
9
Grovyle
EXPOP Series 47/172006Uncommon
$59.73
Ungraded
PSA 10 $199
Strong data
10
Mudkip
EXPOP Series 411/172006Common
$40.00
Ungraded
Moderate data
Mudkip leaps mouth-wide-open out of a curling ocean wave, orange fins flared, with palm trees and a sparkling tropical sky behind it, art by Masakazu Fukuda. Cards from the POP Series promo packs saw far less circulation than main expansion releases, so even a Common like this draws Mudkip fans and anyone chasing the small, scattered POP sets from the EX era.
11
Pidgey
EXPOP Series 412/172006Common
$33.99
Ungraded
PSA 10 $420
Strong data
12
Combusken
EXPOP Series 46/172006Uncommon
$28.15
Ungraded
PSA 10 $740
Strong data
13
Flygon
EXPOP Series 43/172006Rare
$23.58
Ungraded
PSA 10 $1,000
Moderate data
14
Treecko δ
EXPOP Series 415/172006Common
$20.00
Ungraded
PSA 10 $650
Strong data
15
Heal Energy
EXPOP Series 48/172006Uncommon
$16.88
Ungraded
Strong data
16
Wobbuffet
EXPOP Series 416/172006Common
$9.45
Ungraded
Strong data
17
Scramble Energy
EXPOP Series 410/172006Uncommon
$8.29
Ungraded
Strong data

Graded

Ungraded, PSA 9 and PSA 10: the top 5

Deoxys ex, POP Series 4 17/17

Ungraded
$1,000
PSA 9
$375
0.4x the ungraded price
PSA 10
$17,306
17.3x the ungraded price

Ungraded, PSA 9 and PSA 10 values of the top 5 cards, with the PSA 10 multiple of the ungraded price
Card	Ungraded	PSA 9	PSA 10	PSA 10 ÷ ungraded
Deoxys ex 17/17	$1,000	$375	$17,306	17.3x
Chimecho δ 1/17	$946	$1,018	$11,700	12.4x
Pokémon Fan Club 9/17	$475	$593	$2,650	5.6x
Mew 4/17	$375	$3,000	$4,068	10.8x
Sceptile 5/17	$233	$690	$1,536	6.6x

Graded values are read from sales of slabbed copies. When grading pays.

Common questions

What is the most expensive POP Series 4 card?

Deoxys ex 17/17, at $1,000 ungraded and $17,306 as a PSA 10.

How many POP Series 4 cards are worth over $100?

Of the 17 POP Series 4 cards with a price, 6 are worth $100 or more ungraded and 1 is worth $1,000 or more. The rest sell for less, most of them for a few dollars.

What makes a POP Series 4 card valuable?

Scarcity, condition and demand for the character. 5 of the top 10 here are Rare cards. Condition is the other lever: Deoxys ex 17/17 is worth $1,000 ungraded and $17,306 as a PSA 10, 17.3 times more.

How often are these prices updated?

Every day. The prices on this page were last read Nov 12, 2026, from recorded sales of each card.

How this list is ranked

Cards are ordered by their current ungraded value. A PSA 10 copy of a card can be worth many times more, which is why graded values are shown but kept out of the order. Only English-language cards are included. How we price cards